Antibacterial activity, synthesis and characterization of a new Ag(I) and Pd(II) complexes with N-heterocyclic carbene

Prof. Dr. Mohammed Z.  Ghdhayeb; Mohammad Kadhum Talib

doi:10.36329/jkcm/2023/v2.i10.11877

Antibacterial activity, synthesis and characterization of a new Ag(I) and Pd(II) complexes with N-heterocyclic carbene

Authors

Prof. Dr. Mohammed Z. Ghdhayeb Department of chemistry, College of science, Kufa University.
Mohammad Kadhum Talib Department of Chemistry, Faculty of Science, University of Kufa, Najaf, Iraq

DOI:

https://doi.org/10.36329/jkcm/2023/v2.i10.11877

Keywords:

Imidazolium salts, , carbene, Ag(I)-NHC, Ligands-Heterocyclic carbene

Abstract

Preparation of new complexes of silver(I) and palladium(II)-NHC using imidazolium salts were derived through methylimidazole with 2-chloro-N-(4-chlorophenyl) acetamide under certain conditions of temperature and certain solvents, to be synthesized silver complex from the reaction of substituted imidazolium salts with Ag2O using in situ deprotonation technique giving derived structures in good yield. To synthesis Pd(II)-NHC complexes were used Ag(I)-NHC complexes were used as transfer reagents using the transmetallation technique to prepare their respective. The free ligands and their complexes were characterized based on (FT-IR, Melting point, TLC, 1HNMR, 13C-NMR, high-resolution mass spectra and UV). The biological activity studies show

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Published

2023-11-05

How to Cite

Ghdhayeb, P. D. M. Z. ., & Mohammad Kadhum Talib. (2023). Antibacterial activity, synthesis and characterization of a new Ag(I) and Pd(II) complexes with N-heterocyclic carbene. Journal of Kufa for Chemical Sciences, 2(10), 256–269. https://doi.org/10.36329/jkcm/2023/v2.i10.11877

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Issue

Vol. 2 No. 10 (2023): Journal Of Kufa For Chemical Sciences

Section

Peer-reviewed Articles

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This work is licensed under a Creative Commons Attribution 4.0 International License.

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