Preparation and Characterization of Some Transition Metal Complexes with New Schiff Base Ligand Derived from Benzophenone
Abstract
 The preparation and characterization of Co(II), Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) chelate complexes of new Schiff base 2,2̀-dihydroxy-4,4̀-dimethoxy benzopheneden thiosemicarbazone BPHTSC are reported. Structural features were obtained from their elemental analysis, magnetic moment, molar conductance and spectral Uv.Vis and IR measurements. The data show that these complexes have composition of [ML2] type. The Uv-Vis and magnetic susceptibility data of the complexes suggest octahedral geometry of all complexes and the ligand BPHTSC behaves as mono basic tridentate ligand, by coordination through the nitrogen and sulfur/oxygen atoms.
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