Synthesis, characterization and analytical study of new azo ligand driven from benzocaine and its metal complexes

Abstract

The synthesis and spectrum of of a new azo ligand derived from acetylacetone and benzocaine (Ethyl p-aminobenzoate)). Spectral investigations such as 1H NMR,FT.IR, 13C-NMR and Mass spectra were performed to investigate the azo dye ligand's structure. Several physiochemical approaches, FT-IR, electronic spectra, molar conductivity, atom absorption, and magnetic susceptibility were used to identify new complexes with CO(II), and Zn(II) ions Complexes that are all 1:2 [M:L] were formed using the procedures described, and an tetrahedral geometry with sp3 hybridization. At several pH ranges (2–12), the electronic spectra of these azo dyes have been examined in terms of their acid–base properties, which included determining their isosbestic points and protonation and ionization constants. In the other study, azodye were used as an inductor for acid-base titration.