Preparation, Characterization And Biological Study of New Azo-Oxime Ligand And Some of Its Metal Complexes

Authors

  • Israa Karim Abid Aoun
  • Abbas h Khafagy
  • Abid Allah m ali

Abstract

       New chelate compounds, with general formula [M (HL)2(H2O)2]. when [M= Co(II), Ni(II), and Cu(II)] and [M (HL)2].(H2O)2 for Zn(II) and Cd(II), were prepared by reacting chloride salts of these metal with new azo-oxime ligand 2-Hydroxy(3-trifloromethylphenylazo)-benzaldehydeoxime (H2L), which was prepared by coupling of diazonium salt of 3-Methylanilin with Salicylaldoxime. The new azo-oxime ligand and its chelate complexes were characterized by available techniques and the results showed that Co(II), Ni(II), and Cu(II)] chelate complexes have octahedral geometry where Zn(II) and Cd(II), have tetrahedral geometry. The ligand and their metal complexes was tested invitro against the sensitive organisms Staphyllococcus aureus, Streptococcus mutants, Escherichia coli and Proteus mirabilis as antibacterial and Aspergillus  flavus,  Aspergillus terreus as fungicidal. The activity data show that the metal complexes higher antibacterial and antifungus activity than the free ligand.

Keywords: preparation, Azo -oxime, chelate complexes, Biological Study.

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Published

2018-01-09

How to Cite

Abid Aoun, I. K., Khafagy, A. h, & ali, A. A. m. (2018). Preparation, Characterization And Biological Study of New Azo-Oxime Ligand And Some of Its Metal Complexes. Journal of Kufa for Chemical Sciences, 2(3). Retrieved from https://journal.uokufa.edu.iq/index.php/jkcs/article/view/3387

Issue

Vol. 2 No. 3 (2017): المجلد 2 العدد 3 لسنة 2017

Section

Peer-reviewed Articles

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Copyright (c) 2018 مجلة الكوفة للكيمياء | Kufa Journal for Chemistry

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