Extraction of Nickel (II) From Aqueous Solutions By Using 2-[ (4-Bromo Phenyl) Azo]-4,5-Diphenyl Imidazole
Abstract
The extraction of Nickel has been studied as complex with 2-[ (4-Bromo phenyl) azo]-4,5-diphenyl imidazole which dissolved in chloroform .This search comprises the following aspects: the optimum pH values for extraction was (pHext. = 9 ), so the suitable concentration of Ni(II) ions in aqueous solution which is giving highest distribution ratio (D) was (80 μg ) ,studying effect of extraction time illustrated the optimum shaking time to reach the equilibria was ten minute .It was found from experiments that the best value of  D when the concentration of ligand equal  to [3x10-5 M  ] , from other hand organic solvents shows that there is no linear relation ship between dielectric constant of organic solvents and distribution ratio (D) of extraction ,but there is an effect for the organic solvent structure. The thermodynamic study demonstrates the complexation reaction is an exothermic at temperature degrees (20 0C - 70 0C).
Downloads
Downloads
Published
Issue
Section
License
Copyright (c) 2022 Ibtehaj Raheem Ali, Nahla Fathi Makki, Nassir Abd Al-hassan Nassir
This work is licensed under a Creative Commons Attribution 4.0 International License.
which allows users to copy, create extracts, abstracts, and new works from the Article, alter and revise the Article, and make commercial use of the Article (including reuse and/or resale of the Article by commercial entities), provided the user gives appropriate credit (with a link to the formal publication through the relevant DOI), provides a link to the license, indicates if changes were made and the licensor is not represented as endorsing the use made of the work.
