REDUCING WEAR AND POWER CONSUMPTION IN TRIBOLOGICAL SYSTEMS USING CARBON-BASED NANO-LUBRICANTS: AN EXPERIMENTAL STUDY
DOI:
https://doi.org/10.30572/2018/KJE/160318Keywords:
Hydrothermal carbonization, Carbon nanoparticle, Power consumption, Wear, Thermal conductivity, ViscosityAbstract
This study presents a novel approach for producing carbon-based nano-lubricants, which avoids exposure to dry nanopowders usually used in production processes, thereby minimizing the health risks associated with nanoparticles. Furthermore, it adheres to green chemistry principles, as it does not involve toxic solvents or surfactants. In this approach, glucose, the most abundant and cost-effective monosaccharide in most crops, was subjected to hydrothermal carbonization to produce carbon-based aqueous nanofluid. The nanofluid was then mixed with a base oil (SAE 15W-40) at calculated volume ratios. The resulting mixtures were heated to evaporate the water, resulting in 5, 10, 15 and 20 g/l (i.e., 0.25 %, 0.5 %, 0.75 % and 1 % volumetric concentration) stable carbon-based nano-lubricants. In addition to the characterizations of the nano-lubricants, including viscosity and thermal conductivity, power consumption and wear measurements of a tribological system were conducted. The findings revealed linear relationships between nanoparticle concentration and viscosity, thermal conductivity, power reduction, and wear reduction. The maximum thermal conductivity enhancement and viscosity increase were 6 %, and 9.95 % for a 20 g/l nano-lubricant, respectively. Additionally, the power and the wear reductions were 16.66 % at full load, and 52.5 % for the 20 g/l nano-lubricant
Downloads
References
Alazemi, A.A., Alzubi, F.G., Alhazza, A., Dysart, A., Pol, V.G., 2020. Rheological and Wettability Properties of Engine Oil with a Submicron Spherical Carbon Particle Lubricant Mixture. International Journal of Automotive Technology 21, 1475–1482. https://doi.org/10.1007/s12239-020-0139-z
Al-Jeboori, Y., Kosarieh, S., Morina, A., Neville, A., 2018a. Investigation of pure sliding and sliding/rolling contacts in a DLC/Cast iron system when lubricated in oils containing MoDTC-Type friction modifier. Tribol Int 122, 23–37. https://doi.org/10.1016/j.triboint.2018.02.015
Al-Jeboori, Y., Kosarieh, S., Ofune, M., Morina, A., Neville, A., 2018b. Measuring tappet rotation in a valvetrain rig when lubricated in a fully formulated oil containing MoDTC-type friction modifier. Tribol Int 121, 442–449. https://doi.org/10.1016/j.triboint.2018.01.061
Al-Jeboori, Y., Kosarieh, S., Ofune, M., Neville, A., Morina, A., 2020. The effect of clearance between tappet insert and camlobe on the tribological and tribochemical performance of cam/follower surfaces. Tribol Int 149. https://doi.org/10.1016/j.triboint.2018.09.021
Arear, W.F., Zeiny, A., Al-Baghdadi, M., 2021. Influence of Al 2 O3-Water Nanofluid Coolant on Thermal Performance of Hydrogen PEM Fuel Cell Stacks. IOP Conf Ser Mater Sci Eng 1094, 012064. https://doi.org/10.1088/1757-899X/1094/1/012064
Chen, C., Sun, X., Jiang, X., Niu, D., Yu, A., Liu, Z., Li, J.G., 2009. A two-step hydrothermal synthesis approach to monodispersed colloidal carbon spheres. Nanoscale Res Lett 4, 971–976. https://doi.org/10.1007/S11671-009-9343-5
Chinas-Castillo, F., Spikes, H.A., 2003. Mechanism of action of colloidal solid dispersions. J Tribol 125, 552–557. https://doi.org/10.1115/1.1537752
Ettefaghi, E. o. llah, Rashidi, A., Ahmadi, H., Mohtasebi, S.S., Pourkhalil, M., 2013. Thermal and rheological properties of oil-based nanofluids from different carbon nanostructures. International Communications in Heat and Mass Transfer 48, 178–182. https://doi.org/10.1016/j.icheatmasstransfer.2013.08.004
Francis, A.P., Devasena, T., 2018. Toxicity of carbon nanotubes: A review. Toxicol Ind Health 34, 200–210. https://doi.org/10.1177/0748233717747472
Frycz, M., Labuda, M., 2021. AN ANALYSIS OF THE INFLUENCE OF CARBON NANOPARTICLES ADDITIVE ON SELECTED PROPERTIES OF LUBRICATING OILS. Tribologia 296, 7–20. https://doi.org/10.5604/01.3001.0015.5859
Ginzburg, B.M., Shibaev, L.A., Kireenko, O.F., Shepelevskii, A.A., Baidakova, M. V, Sitnikova, A.A., 2002. Antiwear Effect of Fullerene C 60 Additives to Lubricating Oils, Original Russian Text Copyright + 2002 by Ginzburg.
Gulzar, M., Masjuki, H.H., Kalam, M.A., Varman, M., Zulkifli, N.W.M., Mufti, R.A., Zahid, R., 2016. Tribological performance of nanoparticles as lubricating oil additives. Journal of Nanoparticle Research 18, 223. https://doi.org/10.1007/s11051-016-3537-4
Holmberg, K., Andersson, P., Erdemir, A., 2012. Global energy consumption due to friction in passenger cars. Tribol Int 47, 221–234. https://doi.org/10.1016/j.triboint.2011.11.022
Holmberg, K., Andersson, P., Nylund, N.-O., Mäkelä, K., Erdemir, A., 2014. Global energy consumption due to friction in trucks and buses. Tribol Int 78, 94–114. https://doi.org/10.1016/j.triboint.2014.05.004
Holmberg, K., Erdemir, A., 2019. The impact of tribology on energy use and CO2 emission globally and in combustion engine and electric cars. Tribol Int 135, 389–396. https://doi.org/10.1016/j.triboint.2019.03.024
Holmberg, K., Erdemir, A., 2017a. Influence of tribology on global energy consumption, costs and emissions. Friction 5, 263–284. https://doi.org/10.1007/s40544-017-0183-5
Holmberg, K., Erdemir, A., 2017b. Influence of tribology on global energy consumption, costs and emissions. Friction. https://doi.org/10.1007/s40544-017-0183-5
Hu, Z.S., Lai, R., Lou, F., Wang, L.G., Chen, Z.L., Chen, G.X., Dong, J.X., 2002. Preparation and tribological properties of nanometer magnesium borate as lubricating oil additive, Wear.
Huang, H.D., Tu, J.P., Gan, L.P., Li, C.Z., 2006. An investigation on tribological properties of graphite nanosheets as oil additive. Wear 261, 140–144. https://doi.org/10.1016/j.wear.2005.09.010
Huang, H.D., Tu, J.P., Zou, T.Z., Zhang, L.L., He, D.N., 2005. Friction and wear properties of IF-MoS2 as additive in paraffin oil. Tribol Lett 20, 247–250. https://doi.org/10.1007/s11249-005-8552-z
Karna, P., Ghimire, M., Mishra, S., Karna, S., 2017. Synthesis and Characterization of Carbon Nanospheres. OAlib 04, 1–7. https://doi.org/10.4236/oalib.1103619
Ku, B.C., Han, Y.C., Lee, J.E., Lee, J.K., Park, S.H., Hwang, Y.J., 2010. Tribological effects of fullerene (C60) nanoparticles added in mineral lubricants according to its viscosity. International Journal of Precision Engineering and Manufacturing 11, 607–611. https://doi.org/10.1007/s12541-010-0070-8
Lam, C.-W., 2003. Pulmonary Toxicity of Single-Wall Carbon Nanotubes in Mice 7 and 90 Days After Intratracheal Instillation. Toxicological Sciences 77, 126–134. https://doi.org/10.1093/toxsci/kfg243
Liang, H., Zhang, H., Wang, Q., Xu, C., Geng, Z., She, D., Du, X., 2021. A novel glucose-based highly selective phosphate adsorbent. Science of The Total Environment 792, 148452. https://doi.org/10.1016/j.scitotenv.2021.148452
Liu, G., Li, X., Qin, B., Xing, D., Guo, Y., Fan, R., n.d. Investigation of the mending effect and mechanism of copper nano-particles on a tribologically stressed surface.
Liu, J.-H., Wang, T., Wang, H., Gu, Y., Xu, Y., Tang, H., Jia, G., Liu, Y., 2015. Biocompatibility of graphene oxide intravenously administrated in mice—effects of dose, size and exposure protocols. Toxicol Res (Camb) 4, 83–91. https://doi.org/10.1039/C4TX00044G
Liu, L., Zhou, M., Jin, L., Li, L., Mo, Y., Su, G., Li, X., Zhu, H., Tian, Y., 2019. Recent advances in friction and lubrication of graphene and other 2D materials: Mechanisms and applications. Friction 7, 199–216. https://doi.org/10.1007/s40544-019-0268-4
Lv, X., Cao, L., Yang, T., Wan, Y., Gao, J., 2020. Lubricating behavior of Submicrometer carbon spheres as lubricant additives. Particulate Science and Technology 38, 568–572. https://doi.org/10.1080/02726351.2019.1565790
Nunn, N., Mahbooba, Z., Ivanov, M.G., Ivanov, D.M., Brenner, D.W., Shenderova, O., 2015. Tribological properties of polyalphaolefin oil modified with nanocarbon additives. Diam Relat Mater 54, 97–102. https://doi.org/10.1016/j.diamond.2014.09.003
Rapoport, L., Leshchinsky, V., Lvovsky, M., Nepomnyashchy, O., Volovik, Y., Tenne, R., 2002. Mechanism of friction of fullerenes. Industrial Lubrication and Tribology 54, 171–176. https://doi.org/10.1108/00368790210431727
Sadiq Al-Baghdadi, M.A.R., Noor, Z.M.H., Zeiny, A., Burns, A., Wen, D., 2020. CFD analysis of a nanofluid-based microchannel heat sink. Thermal Science and Engineering Progress 20. https://doi.org/10.1016/j.tsep.2020.100685
Shang, W., Cai, T., Zhang, Y., Liu, D., Liu, S., 2018a. Facile one pot pyrolysis synthesis of carbon quantum dots and graphene oxide nanomaterials: All carbon hybrids as eco-environmental lubricants for low friction and remarkable wear-resistance. Tribol Int 118, 373–380. https://doi.org/10.1016/j.triboint.2017.09.029
Shang, W., Ye, M., Cai, T., Zhao, L., Zhang, Y., Liu, D., Liu, S., 2018b. Tuning of the hydrophilicity and hydrophobicity of nitrogen doped carbon dots: A facile approach towards high efficient lubricant nanoadditives. J Mol Liq 266, 65–74. https://doi.org/10.1016/j.molliq.2018.06.042
Sui, T., 2021a. Nano Lubricant Additives, in: Progress in Lubrication and Nano- and Biotribology. CRC Press, Boca Raton, pp. 29–50. https://doi.org/10.1201/9781003096443-2
Sui, T., 2021b. Nano Lubricant Additives, in: Progress in Lubrication and Nano- and Biotribology. CRC Press, Boca Raton, pp. 29–50. https://doi.org/10.1201/9781003096443-2
Sun, X., Li, Y., 2004. Colloidal Carbon Spheres and Their Core/Shell Structures with Noble‐Metal Nanoparticles. Angewandte Chemie 116, 607–611. https://doi.org/10.1002/ange.200352386
Szeri, A.Z., 1998. Fluid Film Lubrication. Cambridge University Press. https://doi.org/10.1017/CBO9780511626401
Tao, X., Jiazheng, Z., Kang, X., 1996. The ball-bearing effect of diamond nanoparticles as an oil additive, J. Phys. D: Appl. Phys.
Wu, P., Chen, X., Zhang, C., Zhang, Jiping, Luo, J., Zhang, Jiyang, 2021. Modified graphene as novel lubricating additive with high dispersion stability in oil. Friction 9, 143–154. https://doi.org/10.1007/s40544-019-0359-2
Wu, Y.Y., Tsui, W.C., Liu, T.C., 2007. Experimental analysis of tribological properties of lubricating oils with nanoparticle additives. Wear 262, 819–825. https://doi.org/10.1016/j.wear.2006.08.021
Xie, H., Jiang, B., He, J., Xia, X., Pan, F., 2016. Lubrication performance of MoS2 and SiO2 nanoparticles as lubricant additives in magnesium alloy-steel contacts. Tribol Int 93, 63–70. https://doi.org/10.1016/j.triboint.2015.08.009
Zeiny, A., Al-Baghdadi, M.A.R., Arear, W.F., Ismail, M.S., 2022. Al2O3–H2O nanofluids for cooling PEM fuel cells: A critical assessment. Int J Hydrogen Energy 47, 38823–38836. https://doi.org/10.1016/j.ijhydene.2022.09.040
Zeiny, A., Haruna, M.A., Wen, D., 2019. Aqueous lithium bromide nanosolution for solar absorption refrigeration systems 020083. https://doi.org/10.1063/1.5117010
Zhou, J., Yang, J., Zhang, Z., Liu, W., Xue, Q., 1999. STUDY ON THE STRUCTURE AND TRIBOLOGICAL PROPERTIES OF SURFACE-MODIFIED Cu NANOPARTICLES, Materials Research Bulletin.
Downloads
Published
Issue
Section
Categories
License
Copyright (c) 2025 Aimen Zeiny, Ward F. Arear, Qasim H. Hassan, Abbas A. Diwan, Luay S. Alansari

This work is licensed under a Creative Commons Attribution 4.0 International License.












